LSRE-LCM - Artigos em Revistas Nacionais e de Circulação Internacional
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- Anaerobic Mesophilic Co-Digestion of Swine Slurry and Hidrolyzate in Batch Reactors: A Case StudyPublication . Domingues, Paulo S.; Pala, Helena; Oliveira, Nelson S.The management of residual flows from swine farms, such as slurry and hydrolyzate, is a serious environmental problem in Portugal, so the search for new solutions is important, especially if they can be implemented in production sites, avoiding the transport of waste. Anaerobic co-digestion can configure a sustainable method of management and valorization of these flows in swine farms, resulting in biogas to produce energy and a digestate with agronomic value. The swine hydrolyzate is the product from the elimination of swine carcasses on the farms, through a hydrolysis process. Its use in the anaerobic process wasn’t found in the literature, identifying the need to evaluate its potential. Thus, anaerobic co-digestion of swine slurry and hydrolyzate was carried out and the main purpose of this research was to find the best feeding ratio between the two substrates in batch test, focusing on biogas production. The study was developed in two phases, both under mesophilic conditions. In the first one, using 100 ml syringes, the effect of the relative proportion of substrates on the anaerobic co-digestion potential was investigated and the effect of pressure sterilization of the substrates on biogas production was verified. In the second phase, a larger scale study was carried out in a 4,500 ml digestor, ran under the conditions identified as the most favorable in the preliminary tests. The results obtained allowed us to conclude that the largest volume of accumulated biogas was obtained with the proportion of 90.9% swine slurry: 9.1% swine hydrolyzate (v/v); and that the sterilization of the substrates doesn’t constitute an effective thermal pre-treatment. The larger scale test revealed an inefficient anaerobic process due to the inhibitory effect caused by the accumulation of ammonia and volatile organic acids. However, the production yield was 606.8 LBiogas/kgVS and 431.6 LMethane/kgVS, indicating that process allowed a production of biogas and methane higher than the values cited in literature for anaerobic digestion of swine slurry. This result showed that the use of swine hydrolyzate as a co-substrate results in a better balance of nutrients, promoting a better development of microorganisms.
- Low-Protein Diets, Malnutrition, and Bone Metabolism in Chronic Kidney DiseasePublication . Pereira, Cidália D.; Guimarães, Carla; Ribeiro, Vânia S.; Vaz, Daniela C.; Martins, Maria JoãoChronic kidney disease (CKD) has a high prevalence worldwide, with increasing incidence in low- and middle-income countries, and is associated with high morbidity and mortality, particularly from cardiovascular disease. Protein-restricted diets are one of the most widely used non-pharmacological approaches to slow the progression of CKD and prevent associated metabolic abnormalities. However, some concerns have been raised about the long-term safety of these diets, particularly with regard to patients’ nutritional status and bone and mineral disorders. Therefore, the aim of this article is to review the most recent scientific evidence on the relevance of using protein-restricted diets (with or without keto-analogue supplementation) and, in particular, their relationships with malnutrition and mineral and bone disorders in people with CKD without kidney replacement therapies. Although protein-restricted diets, especially when supplemented with keto-analogues and highly personalized and monitored, do not appear to be associated with malnutrition, research on their effects on bone and mineral disorders is scarce, deserving further investigation.
- Should Children Drink Water with Very Low Mineral Content? Implications of the Global Expansion of Water Filtration Systems and Relevance of Consumption of Water with Higher Mineralization LevelsPublication . Pereira, Cidália D.; Martins, Maria JoãoThe consumption of water with very low mineral content (W-VLMC; water with total dissolved solids below 50 mg/L), despite limited and inconsistent evidence and the resulting knowledge gaps, has not been associated with health risks for the general population. However, certain population subgroups (those eating very unbalanced diets or avoiding certain foods, engaged in prolonged periods of fasting, and/or doing prolonged or strenuous exercise as well as pregnant or breastfeeding women) should be mindful of maintaining sufficient intake of all essential minerals through their food if regularly using this type of water as their main beverage. The rapid expansion of water filtration systems—often producing W-VLMC—creates a timely and valuable opportunity to advance research on the health implications of W-VLMC intake. As these systems become increasingly common in educational settings and homes, children represent a subgroup experiencing rising exposure to W-VLMC. Additional studies are needed to assess the health effects of such exposure from early childhood. A complementary yet contrasting perspective is that the use of water intended for human consumption—with stringent quality control standards—and natural mineral waters—inherently pure, thus eliminating the need for filtration—with higher mineralization in both types of water, may provide an additional dietary source of essential minerals, especially for all the population subgroups mentioned above.
- Adsorption Behavior and Mechanism of Oxytetracycline on Rice Husk Ash: Kinetics, Equilibrium, and Thermodynamics of the ProcessPublication . Andrade, Christhel A.; Zambrano-Intriago, Luis Angel; Oliveira, Nelson S.; Vieira, Judite S.; Quiroz-Fernández, Luis Santiago; Rodríguez-Díaz, Joan ManuelThe main objective of the present study is to determine the kinetics, thermodynamics, and adsorption mechanism of the oxytetracycline (OTC) on rice husk ash (RHA). The adsorbent was characterized by scanning electronic microscopy, Fourier transform infrared spectroscopy, and nitrogen physisorption. Batch studies were carried out to evaluate the influence of the adsorbent dose, initial concentration, contact time, temperature, and initial pH. RHA was characterized as having heterogeneous, fibrous, and porous particles, consisting predominantly of silica. The removal of OTC depends on the pH of the medium, which is favored at acid pH values. The kinetic data followed the Bangham model, which indicated an OTC diffusion in the pores of RHA, although this was not the only process, as demonstrated through the use of the Weber-Morris model (IPD model). The Sips isotherm best represents the experimental results of the equilibrium study. It was found that the adsorption process was spontaneous and endothermic. The highest adsorption capacity was found at a pH in the range of 4–6, when the OTC is in its zwitterion form and the surface of the RHA is positively charged, thus permitting electrostatic interactions and the formation of hydrogen bonds between the adsorbent and adsorbate molecules. These findings demonstrate the potential of rice husk ash to remove oxytetracycline from water.
- The Effect of a Naturally Ventilated Roof on the Thermal Behaviour of a Building under Mediterranean Summer ConditionsPublication . Ramos, João; Aires, LuisWith the increasing cost associated with energy consumption, climate change and the greater awareness of the population to issues related to energy and environmental efficiency, energy conservation in buildings has been encouraged, along with the development of several solutions based on a more sustainable construction. Building cooling is the most challenging issue in the Mediterranean climate. The roof is one of the main elements of the building’s opaque envelope, where the choice of materials and the implementation of appropriate passive technologies determine the thermal performance of a building. The present work aims to assess the impact of natural ventilation of a roof cavity on the thermal environment of a dwelling house under Mediterranean summer conditions. An experimental study was developed in a small-scale prototype of a typical dwelling house, comprising a ceramic tile roof with vented eaves and insulated sub-tile panels according to the construction solution of the Humbelino Monteiro SA company. The thermal performance of this roof solution was assessed under real climatic conditions based on continuous measurements of the air velocity inside the air gap, the temperature of the air and the surface temperature of all roof layers. Weather conditions were also monitored continuously. Connected with the heat transfer mechanisms, the obtained temperature and air velocity profiles data were analysed and discussed.
- Metal alginates for polyphenol delivery systems: Studies on crosslinking ions and easy-to-use patches for release of protective flavonoids in skinPublication . Silva, João; Vanat, Pavlo; Marques da Silva, Dorinda; Rodrigues, Joaquim Rui; Lagoa, RicardoIncorporation of bioactive natural compounds like polyphenols is an attractive approach for enhanced functionalities of biomaterials. In particular flavonoids have important pharmacological activities, and controlled release systems may be instrumental to realize the full potential of these phytochemicals. Alginate presents interesting attributes for dermal and other biomaterial applications, and studies were carried here to support the development of polyphenol-loaded alginate systems. Studies of capillary viscosity indicated that ionic medium is an effective strategy to modulate the polyelectrolyte effect and viscosity properties of alginates. On gelation, considerable differences were observed between alginate gels produced with Ca2+, Ba2+, Cu2+, Fe2+, Fe3+ and Zn2+ as crosslinkers, especially concerning shrinkage and morphological regularity. Stability assays with different polyphenols in the presence of alginate-gelling cations pointed to the choice of calcium, barium and zinc as safer crosslinkers. Alginate-based films loaded with epicatechin were prepared and the kinetics of release of the flavonoid investigated. The results with calcium, barium and zinc alginate matrices indicated that the release dynamics is dependent on film thicknesses, but also on the crosslinking metal used. On these grounds, an alginate-based system of convenient use was devised, so that flavonoids can be easily loaded at simple point-of-care conditions before dermal application. This epicatechin-loaded patch was tested on an ex-vivo skin model and demonstrated capacity to deliver therapeutically relevant concentrations on skin surface. Moreover, the flavonoid released was not modified and retained full antioxidant bioactivity. The alginate-based system proposed offers a multifunctional approach for flavonoid controllable delivery and protection of skin injured or under risk.
- Degradation of Oxytetracycline in Aqueous Solutions: Application of Homogeneous and Heterogeneous Advanced Oxidative ProcessesPublication . Giler-Molina, José Miguel; Zambrano-Intriago, Luis Angel; Quiroz-Fernández, Luis Santiago; Napoleão, Daniella Carla; Vieira, Judite dos Santos; Oliveira, Nelson Simões; Rodríguez-Díaz, Joan ManuelOxytetracycline is one of the antibiotics most frequently used in the Shrimp Industry during the control of bacterial diseases. These emerging pollutants, which appear in low concentrations, are persistent and alternative treatments and are required for their elimination. The degradation of oxytetracycline was evaluated in an aqueous solution by applying homogeneous (UV/H2O2 and photo-Fenton) and heterogeneous (UV/TiO2 /H2O2) advanced oxidative processes (AOPs). The studies were carried out using a bench reactor with short-wave ultraviolet lamps (UV-C). We quantified the extent to which the degradation of the drug had been efficient by employing highly efficient liquid chromatography (HPLC) and a PDA detector with a wavelength of 354 nm and a C18 column. The best results were obtained when applying the UV/H2O2 treatment, which attained a degradation of 97% under the initial conditions of a dose of 8 µL of H2O2 and 120 min of radiation. The pseudo-first order kinetic model proposed by Chan and Chu showed that the experimental results had an adequate fit, with values greater than R2 ≥ 0.95. Toxicity tests were applied to verify the effect of AOPs employed, when the drug was present in low concentrations. The test results demonstrated a decrease in the root growth of the species Lactuca sativa and Daucus carota.