CDRsp - Comunicações em conferências internacionais
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- Feasibility Study of the PET Fines Incorporation into Recycling ProcessesPublication . Nascimento, Bruna Guilherme do; Bozzola, Fernando; Vasco, Joel C.; Parnigoni, Milena; Capela, Carlos; Heleno, Lizete; Gaspar, Marcelo; Oliveira, Nelson S.Circular economy principles focus on the need to preserve natural resources and foster the use of environmentally sustainable practices. Concerning the use of plastics in a circular economy, increasingly demanding solutions have to be developed towards the zero-waste goal sought after by researchers and society alike. Particular attention has been put into the recycling of PET, mainly due to its wide spectrum of use and, consequently, to large volumes of related waste. The PET mechanical recycling process requires these waste materials to be shredded into PET flakes. Following such a procedure, these flakes are pelletized to be used again as feedstock. Considering the main stages of the mechanical recycling processes, which include plastic screening, shredding and washing, significant amounts of end waste materials are generated. This end-waste integrates small scale particles that are designated by plastic fines. Concerning the PET recycling process, the PET fines resulting from its mechanical recycling are not currently valued due to several technical issues, such as their high contamination level and the complexity of sorting them from other small-size particles. Current research focuses on the feasibility of incorporating these PET fines into the film/injection extruders, avoiding this way the need for an intermediate pelletization stage. To allow for such direct incorporation of PET fines into recycling processes, different decontamination and sorting solutions were implemented and tested. The current study is based on analyzing the mechanical properties of PET fines, using laboratory tests such as FTIR, DSC, MFI, moisture content, tensile tests and bending tests. Preliminary results allow foreseeing the successful direct incorporation of PET fines into PET recycling.
- Further remarks on the "Smith is Huq" conditionPublication . Martins-Ferreira, Nelson; Van der Linden, TimWe compare the Smith is Huq condition (SH) with three commutator conditions in semi-abelian categories: first an apparently weaker condition which arose in joint work with Bourn and turns out to be equivalent with (SH), then an apparently equivalent condition which takes commutation of non-normal subobjects into account and turns out to be stronger than (SH). This leads to the even stronger condition that weighted commutators in the sense of Gran, Janelidze and Ursini are independent of the chosen weight, which is known to be false for groups but turns out to be true in any two-nilpotent semi-abelian category.
- Ink Removal on Plastic Films Printed by FlexographyPublication . Bozzola, Fernando; Nascimento, Bruna Guilherme do; Vasco, Joel C.; Silva, Nelson; Lagoa, Fernando; Capela, Carlos; Heleno, Lizete; Gaspar, Marcelo; Oliveira, Nelson S.Plastics are key engineering materials for our society and economy, mainly due to their multifunctionality and ease of processing. Nonetheless, their main drawback is related to the fact that when these cannot be reprocessed, they do generate waste, which leads to several environmental impacts. Therefore, considering plastics’ circularity, minimizing their waste, and the resulting impacts, stresses the need for these to be recyclable. One of the main challenges that concern their recyclability is the deinking of plastic films when printed by flexography. The current technology uses non-bio-based surfactants and non-renewable surfactants, which are harmful to the environment. Therefore, the main objective of current research is to develop an environmentally sustainable process for ink removal on printed post-industrial flexible plastic films using bio-based surfactants. This process focuses on obtaining a deinked plastic that may be reprinted, avoiding this way for inappropriate disposal or reprocessing problems. The value increase of upcycling such post-industrial waste makes it possible to match the quality of the virgin plastic, which is key to carrying out an effective cost analysis of recycled plastic when compared to the new plastic films. Dedicated laboratory deinking procedures were undertaken with transparent polyethylene films printed by flexography with different conditions. Preliminary results show the dedicated experimental ink removal procedure using bio-based surfactants to be effective and environmentally sustainable.
- Thermal analysis of an extrusion system of a 3-D bioprinterPublication . Ribeiro G.S.; Silva J.V.L.; Freitas D.; Bartolo P.; Almeida, Henrique de Amorim; Silveira Z.C.This work presents a finite element thermal analysis of a 3-D bioprinter desktop based on Fused Deposition Modeling (FDM) with applications on tissue engineering, designed by the Centre for Rapid and Sustainable Product Development - Leiria, Portugal. The purpose of this work it is compare three possibilities of temperature control of the machine during the extrusion process, considering the use of a biodegradable polyester (Polycaprolactone - PCL) as raw material. The first two configurations simulate approaches typically adopted in an attempt to keep the polymer as close as possible to 80 °C and prevent its premature solidification at a critical point. The third configuration considers a hypothetical material substitution to enhance thermal conductivity. The results indicate that the first two configurations are not sufficient to achieve total control of the polymer temperature. However, the third configuration show a significant potential to improve the thermal control of the extrusion process.