Percorrer por autor "Duraccio, Donatella"
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- Quiescent and shear-induced non-isothermal crystallization of isotactic polypropylene-based nanocompositesPublication . Silvestre, Clara; Pezzuto, Marilena; Duraccio, Donatella; Mitchell, Geoffrey R.; Cimmino, SossioThe paper reports a study of the effect of the addition of clay nanoparticles on melt rheology, phase structure, and non-isothermal crystallization process of isotactic polypropylene/hydrogenated oligocyclopentadiene (iPP/HOCP) system in quiescent conditions by DSC and under shear applied at different temperatures by SAXS. For both crystallization conditions, the addition of clay and/or HOCP shifts always the crystallization onset to lower values with respect to iPP. These results can be attributed to the diluent effect of HOCP that causes a decrease in the rate of nucleation and grow of the crystals, to the presence of segregated non-crystallizable phases/particles which hinder the transport of macromolecules chains toward the growing nuclei, and to the formation of beta iPP crystals and in the case of shearinduced crystallization to the presence of HPS which seems to reduce, mainly at low Ts, the amount of oriented polymer crystals, which are nuclei for the crystallization. At a given composition, the crystallization temperatures related at the crystallization under shear are always higher that those obtained by quiescent crystallization supporting the idea that the presence of extended chains in these samples act as nucleating agents favoring the crystallization process of iPP.
- Structure–property relationships in polyethylene based films obtained by blow molding as model system of industrial relevancePublication . Duraccio, Donatella; Mauriello, Amalia; Cimmino, Sossio; Silvestre, Clara; Auriemma, Finizia; Rosa, Claudio de; Pirozzi, Beniamino; Mitchell, Geoffrey RobertA method for the study of structure-property relationships of polyethylene (PE)-based films of potential use in food packaging has been set up. The approach has been demonstrated in the case of films obtained by blow-molding using model mixtures of two different polyethylenes, namely a metallocene-made grade of linear low density polyethylene (mLLDPE) and a low density polyethylene (LDPE). We show that physical properties important for numerous applications of these films, such as water vapor and oxygen permeability, toughness and stress strength, are related to the molecular structure and structural and morphological parameters of the blends, in particular, thickness of amorphous layers in lamellar stacks, lamellar thickness, lamellar twisting, and degree and type of branching.