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Time resolved strain dependent morphological study of electrically conducting nanocomposites

datacite.subject.fosEngenharia e Tecnologia
datacite.subject.fosEngenharia e Tecnologia::Engenharia Eletrotécnica, Eletrónica e Informática
datacite.subject.sdg09:Indústria, Inovação e Infraestruturas
dc.contributor.authorKhan, Imran
dc.contributor.authorMitchell, Geoffrey
dc.contributor.authorMateus, Artur
dc.contributor.authorKamma-Lorger, Christina S.
dc.date.accessioned2025-06-27T10:21:11Z
dc.date.available2025-06-27T10:21:11Z
dc.date.issued2015-10
dc.descriptionArticle number - 012034
dc.descriptionPublished under licence by IOP Publishing Ltd Journal of Physics: Conference Series, Volume 646, Electrostatics 2015 12–16 April 2015, Southampton, UK
dc.description.abstractAn efficient and reliable method is introduced to understand the network behaviour of nano-fillers in a polymeric matrix under uniaxial strain coupled with small angle x-ray scattering measurements. The nanoparticles (carbon nanotubes) are conductive and the particles form a percolating network that becomes apparent source of electrical conduction and consequently the samples behave as a bulk conductor. Polyurethane based nanocomposites containing 2% w/w multiwall carbon nanotubes are studied. The electrical conductivity of the nanocomposite was (3.28×10-5s/m).The sample was able to be extended to an extension ratio of 1.7 before fracture. A slight variation in the electrical conductivity is observed under uniaxial strain which we attribute to the disturbance of conductive pathways. Further, this work is coupled with in- situ time resolved small angle x-ray scattering measurements using a synchrotron beam line to enable its measurements to be made during the deformation cycle. We use a multiscale structure to model the small angle x-ray data. The results of the analysis are interpreted as the presence of aggregates which would also go some way towards understanding why there is no alignment of the carbon nanotubes.eng
dc.description.sponsorshipAcknowledgements: The work at IPL was supported by FCT (Portugal). These experiments were performed at the NCD beamline at ALBA Synchrotron with the collaboration of ALBA staff.
dc.identifier.citationImran Khan et al 2015 J. Phys.: Conf. Ser. 646 012034
dc.identifier.doi10.1088/1742-6596/646/1/012034
dc.identifier.issn1742-6588
dc.identifier.issn1742-6596
dc.identifier.urihttp://hdl.handle.net/10400.8/13433
dc.language.isoeng
dc.peerreviewedyes
dc.publisherIOP Publishing
dc.relation.hasversionhttps://iopscience.iop.org/article/10.1088/1742-6596/646/1/012034
dc.relation.ispartofJournal of Physics: Conference Series
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectNanocomposites
dc.subjectnano-fillers
dc.subjectpolymeric matrix
dc.titleTime resolved strain dependent morphological study of electrically conducting nanocompositeseng
dc.typejournal article
dspace.entity.typePublication
oaire.citation.issue1
oaire.citation.titleJournal of Physics: Conference Series
oaire.citation.volume646
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85
person.familyNameKhan
person.familyNameMitchell
person.familyNameMateus
person.givenNameImran
person.givenNameGeoffrey
person.givenNameArtur
person.identifier166356
person.identifier.ciencia-idE41A-ABDD-1FC7
person.identifier.ciencia-id0E1A-9A57-E79A
person.identifier.orcid0000-0003-4594-4067
person.identifier.orcid0000-0001-7977-7610
person.identifier.orcid0000-0003-2483-9153
person.identifier.ridH-3387-2018
person.identifier.scopus-author-id7403103397
person.identifier.scopus-author-id14028690000
relation.isAuthorOfPublicationd3bd5c28-5a13-4284-bf15-593e1a2c2aa4
relation.isAuthorOfPublication48c8066b-023e-4405-b462-49d28af000d1
relation.isAuthorOfPublication1dfafb6b-cec8-4769-ac8e-76dbd0209077
relation.isAuthorOfPublication.latestForDiscoveryd3bd5c28-5a13-4284-bf15-593e1a2c2aa4

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