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Polyethylene and the Nucleating Agent: Dibenzylidene Sorbitol, a Neutron Scattering Study

dc.contributor.authorMitchell, Geoffrey R.
dc.contributor.authorPratumshat, Supatra
dc.contributor.authorOlley, Robert
dc.date.accessioned2023-03-14T11:15:17Z
dc.date.available2023-03-14T11:15:17Z
dc.date.issued2019-04-09
dc.descriptionAcknowledgements: This research was supported by the European Regional Development Fund (FEDER), through COMPETE2020 under the PT2020 program (POCI-01-0145-FEDER-023423), by the Portuguese Foundation for Science and Technology (UID/Multi/04044/2013), (UC4PE and Centro2020 PAMI - ROTEIRO/0328/2013 (Nº 022158).. The SANS measurements were made at the STFC ISIS Facility using the LOQ instrument with the help of ISIS Staff. We are grateful to Dr Stephen King for his help. We thank Naresuan university for supporting SP during her Ph.D. and Faculty of Science Naresuan University for funding short visits.pt_PT
dc.description.abstractDibenzylidene Sorbitol is a very effective clarification additive for isotactic polypropylene. It is not effective with polyethylene although recent studies have shown that it can act as an effective nucleating and directing agent. We employ small-angle neutron scattering measurements to more fully understand the behavior of dibenzylidene sorbitol in a polyethylene matrix. The small-aangle neutron scattering clearly shows that the disappearance of the DBS fibrils is concentration dependent and for 2% DBS the midpoint of the dissolution is at 145°C and for 1% is ~ 20°C lower.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationMitchell, G. R., Pratumshat, S., & Olley, R. (2019). Polyethylene and the Nucleating Agent: Dibenzylidene Sorbitol, a Neutron Scattering Study. Applied Mechanics and Materials, 890, 199–204. https://doi.org/10.4028/www.scientific.net/amm.890.199pt_PT
dc.identifier.doihttps://doi.org/10.4028/www.scientific.net/AMM.890.199pt_PT
dc.identifier.issn1662-7482
dc.identifier.urihttp://hdl.handle.net/10400.8/8214
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherTrans Tech Publicationspt_PT
dc.relationCentre for Rapid and Sustainable Product Development
dc.relation.publisherversionhttps://www.scientific.net/AMM.890.199pt_PT
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectCrystallizationpt_PT
dc.subjectMorphologypt_PT
dc.subjectNanoparticlespt_PT
dc.subjectShearpt_PT
dc.subjectOrientationpt_PT
dc.subjectSmall-angle neutron scatteringpt_PT
dc.titlePolyethylene and the Nucleating Agent: Dibenzylidene Sorbitol, a Neutron Scattering Studypt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleCentre for Rapid and Sustainable Product Development
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UID%2FMulti%2F04044%2F2013/PT
oaire.citation.endPage204pt_PT
oaire.citation.startPage199pt_PT
oaire.citation.titleApplied Mechanics and Materialspt_PT
oaire.citation.volume890pt_PT
oaire.fundingStream6817 - DCRRNI ID
person.familyNameMitchell
person.givenNameGeoffrey
person.identifier166356
person.identifier.ciencia-idE41A-ABDD-1FC7
person.identifier.orcid0000-0001-7977-7610
person.identifier.scopus-author-id7403103397
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication48c8066b-023e-4405-b462-49d28af000d1
relation.isAuthorOfPublication.latestForDiscovery48c8066b-023e-4405-b462-49d28af000d1
relation.isProjectOfPublication9c625981-b187-4078-8cb2-d84b0d21a477
relation.isProjectOfPublication.latestForDiscovery9c625981-b187-4078-8cb2-d84b0d21a477

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